MICRODISC ELECTRODE
ARRAYSTM
(MDEAs) |
MDEA DEVICES |
Number of Discs |
Disc dimensions |
Active Area |
Conductor |
MDEA 360 |
1 disc |
3,600 microns diameter discs |
0.10 cm2 |
Au, Pt, ITO |
MDEA 250 |
207 microdiscs |
250 microns diameter discs |
0.10 cm2 |
Au, Pt, ITO |
MDEA 100 |
1,296 microdiscs |
100 microns diameter discs |
0.10 cm2 |
Au, Pt, ITO |
MDEA 050 |
5,184 microdiscs |
50 microns diameter discs |
0.10 cm2 |
Au, Pt, ITO |
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MDEA Brochure (PDF) |
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Introduction and BackgroundØ Microdisc Electrode Arrays (MDEAs) are inert, array microelectrodes formed from a microlithographically patterned insulator-on-conductor-on-insulator configuration. They are designed for the study of electrochemical and optical properties of thin polymeric films and coatings, for applications in microelectrochemistry, for electrical/electrochemical impedance spectroscopy, and for chemical and biological sensor development. Ø Microfabricated from 100 nm magnetron sputter-deposited gold, e-gun vapor-deposited platinum, or conductive indium tin oxide (ITO) on an electronics grade borosilicate glass, these devices are supplied in three microdisc diameters and corresponding microdisc densities. A 500nm thin silicon nitride layer is applied over the conductor and is microlithographically windowed using reactive ion etching to reveal an array of micro-windows to the metal beneath and a bonding pad. MDEAs are avalable as packaged (with attached leadwires and encapsulated) or as un-packaged die. Ø MDEA chips of gold, platinum, or ITO are available with 50 microns, 100 microns, 250 microns, or 3,600 microns disc diameter. Ø In research and product development, these devices are widely used for conductimetric, chemoresistive chemical and biological sensors using electrically conducting (electroconductive) polymers, for impedance sensors based on Langmuir-Blodgett thin films, for studying environmental effects on polymer thin films, and in modern micro-electrochemistry. Ø Investigate the chemoresistive responses of transducer-active, polymeric thin films in the same electrode configuration, the same test environment, and on the same sample film. Develop these devices into products where the application requires a compact, durable and versatile chemical or biological chemoresistive or electroanalytical sensor of low cost. Back to Index Applications of MDEAsApplications of MDEAs in research and product development include: Ø As conductimetric chemical sensors and biosensors based on electroactive polymers. Such devices exploit the very large change in electrical impedance that accompanies oxidation/reduction of these polymer films. Films are conferred with chemical and biological specificity through the use of inorganic catalysts, organic hosts-guests binding compounds, synthetic antibodies, or molecularly imprionted polymers, and natural biorecognition agents such as enzymes, antibodies and DNA. Ø For the study of electrical and electrochemical impedance spectroscopy of organic thin films and coatings and carbon nanotubes. Ø As a capacitance probe during the deposition or cure of an organic thin film or polymer e.g. Films based on Langmuir-Blodgett thin film deposition or cure of an epoxy. Ø In modern microelectrochemistry -- as generator and collector electrodes in electrochemical amplification or in the performance of electroanalysis in high impedance environments. The microdisc electrode format allows accommodates radial diffusion . Ø In conductimetry studies. To determine the conductance of low conductivity media and in conductimetric titrations. Ø In coatings research and development. For example, to study the transport of water into and through a coating or to study the physical aging of the polymer upon environmental exposure or accelerated aging. Back to Index Technical Specifications |
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Ø Chip Substrate: |
Schott D263 Borosilicate Glass |
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Dielectric Constant, Epsilon(r) at 1 MHz |
6.7 |
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Dielectric Loss Angle, tan delta, at 1 MHz |
61 x 10-4 |
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Electrical Resistivity (50 Hz) (250 C) |
1.6 x 10^8 ohm cm |
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Coefficient of Linear Thermal Expansion, * 20-300 Deg C |
7.2 x 10^-6 K^-1 |
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Refractive Index at 20 C, ne ( Lambda = 546.1 nm) |
1.5249 |
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Ø Metallization: |
100 Å Ti|W / 1000 Å Au or Pt and ITO = 10 Ohms/sq |
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Ø Insulating Top Layer: |
Silicon Nitride (Si3N4) |
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No of Discs |
Electroactive Area (cm2) |
Geometric Area (cm2) |
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Ø MDEA 360 |
A single disc, 3.60 mm in diameter. |
1 |
1.0 x10-1 |
1.0 x10-1 |
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Ø MDEA 250 |
207 separate discs, each 250 mm in diameter and arranged 500 mm on centers in a hexagonal close packaed array. |
207 |
1.0 x10-1 |
4.5 x10-1 |
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Ø MDEA 100 |
1,296 separate discs, each 100 mm in diameter and arranged 200 mm on centers in a hexagonal close packaed array. |
1,296 |
1.0 x10-1 |
4.5 x10-1 |
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Ø MDEA 050 |
5,184 separate discs, each 50 mm in diameter and arranged 100 mm on centers in a hexagonal close packaed array. |
5,184 |
1.0 x10-1 |
4.5 x10-1 |
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Ø MDEA Chip Dimensions |
Un-packaged Die |
Packaged Die |
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(l x w x t) |
(l x w x t) |
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MDEA XXX |
2.00 x 1.00 x 0.05 cm |
13.2 x 1.38 x 0.7 cm |
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Ø Packaging |
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Electrode Body: |
PVC-Jacketed printed circuit board |
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Encapsulant: |
Epoxy header. Polyimide packaged chip. |
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Leadwires: |
Color coded, 28 AWG stranded copper, shielded, and PVC jacketed |
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Back to Index |
Back to Index
MethodsØ Films or coatings may be applied to the MDEA device by dip coating, spin casting, spray painting, air-brushing, brush painting, by Langmuir-Blodgett thin film deposition technique, by electropolymerization, and/or by molecular self assembly. Ø The chip may be immersed in organic, or aqueous medium to a level above the geometric area occupied by microdiscs. Ø Electrical contact is made via bonding pad loacaed on on end of the chip. For further information, request Application Notes or you may download application note files: Microdisc Electrode Array (MDEATM) is the tradename for a family of devices developed by ABTECH. Also called microelectrode arrays, these devices are microfabricated (using microelectronics fabrication techniques) to form patterns of conductors deposited on an insulating substrate chip. |
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Contact:
Ann M. Wilson, Manager,
Applications Development ABTECH
Scientific, Inc.
800 East Leigh Street, Richmond, Virginia
23219
Telephone Number: +1-804-783-7829 Fax Number:
+1-804-783-7830
e-mail: sales@abtechsci.com
Last Revision 04/03/2010, (c) 2000-2010 ABTECH Scientific, Inc.